Employee with 2 account definition - access to IT SHOP

Good evening to everyone,

I have a question and I would like to understand if it's possible to do it or not.

I have multiple employees  with two account definition : ad account and adm ad account,

I would like to log in IT SHOP with employee credentials and choose to log in with, or buy a product and choose wich account will recive the product( ex ad membership , shares access , etc..).

Thank you for help, best regards